Controlled free radical polymerization of vinyl acetate with cobalt acetoacetonate 523 2 2a bulk polymerization of vinyl acetate with co acac 2 catalyst dmf ligand bzpo. Part a 1 1972 10 2853 2866. We first studied the monomer size effect on free radical polymerization by using vinyl esters with different molecular dimensions length width i e vinyl acetate vac 5 9 4 0 å 2 vinyl propionate vpr 6 4 4 0 å 2 2.
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